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I adjusted the equilibrium constant, but the result does not show the Cs+
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Topic: I adjusted the equilibrium constant, but the result does not show the Cs+ (Read 11628 times)
duanjiabin
Frequent Contributor
Posts: 12
I adjusted the equilibrium constant, but the result does not show the Cs+
«
on:
19/12/23 07:57 »
I adjusted the equilibrium constant, but the result does not show the Cs+.
SOLUTION 1
temp 25
pH 7
pe 4
redox pe
units mmol/kgw
density 1
-water 1 # kg
PHASES
Cs2O
H2O + 2Cs+ = Cs2O + 2H+
log_k -89.96
delta_h 511.91 kJ
REACTION 1
Cs2O 1
1 moles in 1 steps
SOLUTION_MASTER_SPECIES
Cs Cs+ 0 132.9054 132.9054
SOLUTION_SPECIES
Cs+ = Cs+
log_k 0
H2O + 2Cs+ = Cs2O + 2H+
log_k -89.68
delta_h 511.91 kJ
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dlparkhurst
Global Moderator
Posts: 4336
Re: I adjusted the equilibrium constant, but the result does not show the Cs+
«
Reply #1 on:
19/12/23 16:01 »
You have not defined any Cs in your solution. Add Cs in SOLUTION, or add Cs2O in EQUILIBRIUM_PHASES.
You PHASES definition is wrong. The mineral formula should be the first item on the left-hand-side of the equation. Cs2O is not a likely mineral phase for most systems.
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duanjiabin
Frequent Contributor
Posts: 12
Re: I adjusted the equilibrium constant, but the result does not show the Cs+
«
Reply #2 on:
21/12/23 06:25 »
Thank you very much for your reply, I have modified it successfully!
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I adjusted the equilibrium constant, but the result does not show the Cs+