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  • I adjusted the equilibrium constant, but the result does not show the Cs+
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Author Topic: I adjusted the equilibrium constant, but the result does not show the Cs+  (Read 11628 times)

duanjiabin

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  • Posts: 12
I adjusted the equilibrium constant, but the result does not show the Cs+
« on: 19/12/23 07:57 »
I adjusted the equilibrium constant, but the result does not show the Cs+.
SOLUTION 1
    temp      25
    pH        7
    pe        4
    redox     pe
    units     mmol/kgw
    density   1
    -water    1 # kg

PHASES
Cs2O
    H2O + 2Cs+ = Cs2O + 2H+
    log_k     -89.96
    delta_h   511.91 kJ

REACTION 1
    Cs2O       1
    1 moles in 1 steps

SOLUTION_MASTER_SPECIES
    Cs            Cs+              0     132.9054        132.9054

SOLUTION_SPECIES
Cs+ = Cs+
    log_k     0
H2O + 2Cs+ = Cs2O + 2H+
    log_k     -89.68
    delta_h   511.91 kJ
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dlparkhurst

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Re: I adjusted the equilibrium constant, but the result does not show the Cs+
« Reply #1 on: 19/12/23 16:01 »
You have not defined any Cs in your solution. Add Cs in SOLUTION, or add Cs2O in EQUILIBRIUM_PHASES.

You PHASES definition is wrong. The mineral formula should be the first item on the left-hand-side of the equation. Cs2O is not a likely mineral phase for most systems.
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duanjiabin

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  • Posts: 12
Re: I adjusted the equilibrium constant, but the result does not show the Cs+
« Reply #2 on: 21/12/23 06:25 »
Thank you very much for your reply, I have modified it successfully!
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