Click here to donate to keep PhreeqcUsers open
Welcome,
Guest
. Please
login
or
register
.
Did you miss your
activation email
?
1 Hour
1 Day
1 Week
1 Month
Forever
Login with username, password and session length
Forum Home
Login
Register
PhreeqcUsers Discussion Forum
»
Conceptual Models
»
Equilibrium assumptions
»
I adjusted the equilibrium constant, but the result does not show the Cs+
« previous
next »
Print
Pages: [
1
]
Go Down
Author
Topic: I adjusted the equilibrium constant, but the result does not show the Cs+ (Read 865 times)
duanjiabin
Frequent Contributor
Posts: 12
I adjusted the equilibrium constant, but the result does not show the Cs+
«
on:
December 19, 2023, 07:57:47 AM »
I adjusted the equilibrium constant, but the result does not show the Cs+.
SOLUTION 1
temp 25
pH 7
pe 4
redox pe
units mmol/kgw
density 1
-water 1 # kg
PHASES
Cs2O
H2O + 2Cs+ = Cs2O + 2H+
log_k -89.96
delta_h 511.91 kJ
REACTION 1
Cs2O 1
1 moles in 1 steps
SOLUTION_MASTER_SPECIES
Cs Cs+ 0 132.9054 132.9054
SOLUTION_SPECIES
Cs+ = Cs+
log_k 0
H2O + 2Cs+ = Cs2O + 2H+
log_k -89.68
delta_h 511.91 kJ
Logged
dlparkhurst
Global Moderator
Posts: 3766
Re: I adjusted the equilibrium constant, but the result does not show the Cs+
«
Reply #1 on:
December 19, 2023, 04:01:47 PM »
You have not defined any Cs in your solution. Add Cs in SOLUTION, or add Cs2O in EQUILIBRIUM_PHASES.
You PHASES definition is wrong. The mineral formula should be the first item on the left-hand-side of the equation. Cs2O is not a likely mineral phase for most systems.
Logged
duanjiabin
Frequent Contributor
Posts: 12
Re: I adjusted the equilibrium constant, but the result does not show the Cs+
«
Reply #2 on:
December 21, 2023, 06:25:06 AM »
Thank you very much for your reply, I have modified it successfully!
Logged
Print
Pages: [
1
]
Go Up
« previous
next »
PhreeqcUsers Discussion Forum
»
Conceptual Models
»
Equilibrium assumptions
»
I adjusted the equilibrium constant, but the result does not show the Cs+