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Example 7, Gas volume
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Topic: Example 7, Gas volume (Read 912 times)
Jeonghwan Hwang
Top Contributor
Posts: 77
Example 7, Gas volume
«
on:
August 16, 2022, 11:36:14 AM »
Hello,
I have a question at Example 7.
At the example code, the volume of gas was calculated by using ideal gas equation as below;
" 40 vol = moles * 0.08207 * TK / 1.1"
When I saw the simulation results, I found the 'Gas volume'
Can anyone advice me what these results mean?
I'm confused because the 'Volume, in liters' at
fixed_pressure
results in USER_Graph2 was not matched with 'Gas volume'
-----------------------------------Gas phase-----------------------------------
Total pressure: 1.10 atmospheres (Peng-Robinson calculation)
Gas volume: 1.13e+00 liters
Molar volume: 2.22e+01 liters/mole
P * Vm / RT: 0.99636 (Compressibility Factor Z)
Moles in gas
----------------------------------
Component log P P phi Initial Final Delta
CH4(g) -0.17 6.818e-01 0.998 0.000e+00 3.152e-02 3.152e-02
CO2(g) -0.43 3.697e-01 0.994 0.000e+00 1.709e-02 1.709e-02
H2O(g) -1.50 3.162e-02 0.993 0.000e+00 1.462e-03 1.462e-03
N2(g) -1.77 1.682e-02 1.000 0.000e+00 7.776e-04 7.776e-04
Thank you,
Sincerely,
Jeonghwan Hwang
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dlparkhurst
Top Contributor
Posts: 3716
Re: Example 7, Gas volume
«
Reply #1 on:
August 16, 2022, 03:32:19 PM »
The gas volume is consistent with the moles in the gas phase.
Code:
[Select]
3.152e-2+1.709e-2+1.462e-3+7.776e-4 = 0.0508496 moles
and
Code:
[Select]
.0508*0.082*298.15/1.1 = 1.1290 L
Note that example 7 is a Peng-Robinson calculation, which corresponds closely to the ideal gas law at low pressures, but will differ at higher temperature and pressure because it uses the Peng-Robinson Equation of State.
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Example 7, Gas volume